• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    In the preparation of acrylonitrile or methacrylonitrile by ammoxidation of propylene or isobutylene with ammonia and molecular oxygen in the vapor phase in the presence of a catalyst comprising silica and supported thereon oxides of molybdenum, bismuth and iron, the yield of acrylonitrile or methacrylonitrile based on ammonia is improved without sacrificing the yield based on propylene or isobutylene by the use of a novel catalyst having, incorporated therein, 0.002 to 0.2 atom, based on 12 atoms of molybdenum, of an oxide of at least one element selected from the group consisting of palladium, platinum, osminum and iridium.
    公开号:SU1496631A3
    申请号:SU864027925
    申请日:1986-08-08
    公开日:1989-07-23
    发明作者:Kinitosi Aoki；Sigeo Nakamura
    申请人:Asahi Chemical Ind；
    IPC主号:
    专利说明:

    The invention relates to medicine, namely to cosmetology. The purpose of the invention is the normalization of metabolic processes in distro2
    visually modified nail plate. Prepare samples of creams in the following ratios of components, May.% - silicone oil 3.0-6.0; perfume oil 3.0-6.0; emulsion wax 2,0-4,0; distilled monoglycerides 1.0-4.0; glycerin 2.0-5.0; stearyl stearate 1.0-3.0; 96 ° ethyl alcohol 1.0-3.0; confectionery fat 1.0-4.0; paraoxybenzoic acid methyl ester 0.1-0.4; paraoxybenzoic acid propyl ester 0.05-0.2; amino acid mixture of autolysates of baking yeast 1.0-5.0; perfume 0.3-0.6; water - the rest. Cream for nail care has a good consistency, smell, does not have an irritating and allergenic effect with prolonged use. After applying the cream, the nail plate becomes smooth, pink, such phenomena as peeling, brittleness, stratification disappear, the growth of the nail improves, and its nutrition by expanding and lengthening the small capillaries of the nail limb.
    The invention relates to medicine, namely to cosmetology.
    The aim of the invention is the normalization of metabolic processes in dystrophic modified nail plate.
    Technology of preparation of the cream.
    The estimated amount of hot (65-70 ° C) water is supplied to a 400-meter metal measuring device. In a portion of the hot water, para-benzoic acid methyl ester is dissolved. The ether is weighed on a dial scale. The mixture of amino acids is dissolved in hot (65 ° C) water in an enamel container. Separately, an amount of 96-degree ethanol is weighed in an enamel container.
    In a cast iron enameled reactor with a capacity of 630 liters, equipped with a steam jacket and anchor stirrer (100 rpm), the following components are loaded in quantities corresponding to the recipe: confectionary fat, stearyl stearate, distilled monoglycerides, emulsion waxes at a temperature of 65 -70 C. e molten mass fed 70% of the calculated amount of perfume oil. The rest of the perfume oil and para-benzoic acid propnl ester is left to flush the pipeline. Then silicone oil is introduced into the mixture. Hot water (70 ° C) is fed in a small stream through the process line through pipe 1496797
    Plenum filter in a cast iron enamelled cooking reactor, also equipped with a propeller stirrer (1500 rpm). The cooking reactor is preheated to 60 ° C.
    Glycerin in an amount corresponding to the formulation, is introduced into the aqueous medium through a nylon filter. An aqueous solution of paraoxybenzoic acid methyl ester is then added. All thoroughly mixed anchor stirrer. Using a gear pump, the melted fat components filtered through a nylon filter are pumped into the cooking reactor. The left amount of perfume oil is washed by a pipeline through which the fatty components were pumped.
    Immediately after the fat components, ethyl alcohol filtered through the filter is introduced into the reactor, then the mixture is emulsified with a propeller stirrer for 20-25 minutes. After that, the propeller stirrer is disconnected and emulsification is continued only with an anchor stirrer.
    In the emulsion, cooled to 45 ° C, a perfume fragrance is supplied. All thoroughly mixed with an anchor stirrer with further cooling to 25 ° C. From the cooking reactor using a pump, the cream is pumped into enamelled containers and the mass is left to crystallize for 12 hours. Packing of the cream is carried out using a pipe-napping machine.
    According to the described technology, samples of creams are prepared with the proportions of the prescription components listed in the table.
    On cleaned nails, the cream is applied evenly for 30-40 minutes, after which the remnants of the cream are removed with a cotton swab or paper towel. The cream is recommended to be applied 2 times a day - in the morning and in the evening and for 30 days.
    Indications: dystrophic changed nails with pronounced peeling, brittleness, fragility, exfoliation, pigmentation, dry skin of the fingers.
    The effectiveness of the proposed cream tested in clinical trials conducted on patients with pronounced dystrophy of the nail plate. It was found that under the action of the cream there is a simultaneous stimulation of fat, protein and water-salt exchanges, which is manifested in an increase in the content of cholesterol, cystine and water in the nail. As a result, the nails become vibrant pink color, peeling, fragility, delamination, transverse and longitudinal grooves disappear. In addition, the number and width of small capillaries of the limb of the nail increases significantly, which indicates an improvement in the nutrition of the nail plate.
    Irritant and allergenic effects of the cream on the skin of the patients' hands were not identified.
    权利要求:
    Claims (1)
    [1]
    Claim
    Cream for nail care, containing glycerin, ethyl alcohol, emulsion waxes, propyl and methyl paraoxybenzoic acid esters, biologically active basis obtained from baking yeast, perfume and water, characterized in that, in order to normalize metabolic processes in dystrophically modified nail plate , the cream additionally contains silicone oil, perfume oil, confectionary fat, monoglycerides, stearyl stearate, and as a biologically active basis, an amino acid mixture from bakery autolysates x yeast in the following ratio of components, May. %:
    Glycerol 2.0-5.0 Ethanol 1.0-3.0 Emulsion waxes 2.0-4.0 Propyl ether hydroxybenzoic acid 0.05—1 Methyl ether hydroxybenzoic acids 0.1-0.4 Amino acid mixture bread autolysates Baking Yeast 1.0-5.0 Silicone oil 3.0-6.0 Perfume oil 3.0-6.0 Confectionery fat 1.0-4.0 Monoglycerides 1.0-4.0 Stearyl stearate 1.0-3.0 Odorant 0.3-0.6 Water Rest
    five
    1496797
    6
    Components The content of the components in the cream according to the examples, wt.% one 2 3 Silicone oil oh oh 5.0 6.0 Perfume oil 3.0 5.0 6.0 Emulsion wax 2.0 oh oh 4.0 Distilled monoglycerides. 1.0 oh oh 4.0 Glycerol 2.0 4.0 5.0 Stearyl stearate 1.0 2.0 3.0 Ethanol 1.0 2.0 oh oh Confectionery fat 1.0 3.0 4.0 Methyl ether hydroxybenzoic acid 0.1 0.3 0.4 Steam propyl ether hydroxybenzoic acid 0.05 0.1 0.2 Amino acid mixture from purified autolysis tov bakery yeast 1.0 2.0 5.0 Odorant 0.3 0.5 0.6 Water Rest The rest The rest a little a little
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    同族专利:
    公开号 | 公开日
    EP0127942B1|1986-08-27|
    EP0127942A1|1984-12-12|
    JPS59204164A|1984-11-19|
    US4600541A|1986-07-15|
    DE3460545D1|1986-10-02|
    JPS6158462B2|1986-12-11|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US2904530A|1956-08-17|1959-09-15|Gen Aniline & Film Corp|Curing agents for epoxy resins|
    CA679979A|1960-12-07|1964-02-11|Knapsack-Griesheim Aktiengesellschaft|Process for preparing unsaturated nitriles|
    US3156735A|1960-12-12|1964-11-10|Shell Oil Co|Oxidative dehydrogenation using goldplatinum group metal catalyst|
    DE1221637B|1964-04-16|1966-07-28|Hoechst Ag|Process for the production of vinyl compounds|
    BE663698A|1964-05-09|
    GB1110682A|1965-04-02|1968-04-24|Asahi Chemical Ind|Process for producing saturated aliphatic nitriles|
    GB1127355A|1965-08-09|1968-09-18|Asahi Chemical Ind|Process for producing unsaturated aliphatic nitriles|
    US3412136A|1965-10-11|1968-11-19|Nat Distillers Chem Corp|Process for the preparation of aliphatic nitriles|
    US3415886A|1967-02-07|1968-12-10|Du Pont|Heat treated bismuth molybdate on silica catalysts|
    US3625867A|1967-06-02|1971-12-07|Takachika Yoshino|Process for production of metal oxide-antimony oxide catalysts|
    US3499025A|1967-09-06|1970-03-03|Sun Oil Co|Method for producing acrylonitrile and methacrylonitrile|
    BE756878A|1969-03-04|1971-03-30|Stamicarbon|PROCESS FOR THE PREPARATION OF A CATALYST SYSTEM FOR THE AMMOXIDATION OF OLEFINS|
    JPS4843096B1|1970-01-31|1973-12-17|
    US3911089A|1972-10-06|1975-10-07|Sumitomo Chemical Co|Process for preparing hydrogen cyanide|
    US4139552A|1974-01-04|1979-02-13|The Standard Oil Company|Production of unsaturated nitriles|
    JPS582232B2|1977-12-31|1983-01-14|Asahi Chemical Ind|
    JPS6126419B2|1981-10-20|1986-06-20|Asahi Chemical Ind|JP2520279B2|1988-03-03|1996-07-31|日東化学工業株式会社|Method for producing acrylonitrile|
    US4981670A|1989-12-15|1991-01-01|Bp America Inc.|HCN from crude aceto|
    GB9226453D0|1992-12-18|1993-02-10|Johnson Matthey Plc|Metal oxide catalyst|
    GB9316955D0|1993-08-14|1993-09-29|Johnson Matthey Plc|Improvements in catalysts|
    US5877377A|1993-08-14|1999-03-02|Johnson Matthey Public Limited Company|Metal oxide catalyst and use thereof in chemical reactions|
    US5780664A|1993-08-17|1998-07-14|Asahi Kasei Kogyo Kabushi Kaisha|Ammoxidation catalyst composition|
    CN1108865C|1997-09-03|2003-05-21|中国石油化工集团公司|Catalyst for production of acrylonitrile|
    US6017846A|1999-01-11|2000-01-25|Saudi Basic Industries Corporation|Highly active and selective catalysts for the production of unsaturated nitriles, methods of making and using the same|
    US6037304A|1999-01-11|2000-03-14|Saudi Basic Industries Corporation|Highly active and selective catalysts for the production of unsaturated nitriles, methods of making and using the same|
    US6284196B1|1999-04-01|2001-09-04|Bp Corporation North America Inc.|Apparatus for monitor and control of an ammoxidation reactor with a fourier transform infrared spectrometer|
    US6486091B1|2000-03-14|2002-11-26|Saudi Basic Industries Corporation|Process for making highly active and selective catalysts for the production of unsaturated nitriles|
    US6337424B1|2000-04-28|2002-01-08|Saudi Basic Industries Corporation|Catalysts oxidation of lower olefins to unsaturated aldehydes, methods of making and using the same|
    US6441227B1|2000-06-23|2002-08-27|Saudi Basic Industries Corporation|Two stage process for the production of unsaturated carboxylic acids by oxidation of lower unsaturated hydrocarbons|
    US8507404B2|2005-07-12|2013-08-13|Exxonmobil Research And Engineering Company|Regenerable sulfur traps for on-board vehicle applications|
    KR101086731B1|2008-10-17|2011-11-25|금호석유화학 주식회사|THE COMPLEX OXIDE CATALYST OF Bi/Mo/Fe FOR THE OXIDATIVE DEHYDROGENATION OF 1-BUTENE TO 1,3-BUTADIENE AND PROCESS THEREOF|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    JP58078290A|JPS6158462B2|1983-05-06|1983-05-06|
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